小中大回复
可以读读下面的3篇文献：
Phys. Chem. Chem. Phys., 2007, 9, 1276 - 1290, DOI: 10.1039/b613962k
Studying disorder in graphite-based systems by Raman spectroscopy
M. A. Pimenta, G. Dresselhaus, M. S. Dresselhaus, L. G. Cançado, A. Jorio and R. Saito
cuturl('http://www.rsc.org/Publishing/Journals/CP/article.asp?doi=b613962k')
J. Chem. Phys. 53, 1126 (1970); doi:10.1063/1.1674108 (5 pages)
Raman Spectrum of Graphite
F. Tuinstra and J. L. Koenig
cuturl('http://jcp.aip.org/jcpsa6/v53/i3/p1126_s1?isAuthorized=no')
Raman Spectroscopy of Carbon Nanotubes in 1997 and 2007
M. S. Dresselhaus,*‡ G. Dresselhaus,§ and A. Jorio
J. Phys. Chem. C, 2007, 111 (48), pp 17887–17893
DOI: 10.1021/jp071378n
cuturl('http://pubs.acs.org/doi/abs/10.1021/jp071378n')
下面的这一段话是从文献J. Phys. Chem. C 2008, 112, 10637–10640的Introduction拷贝出来的。
Raman spectroscopy has historically been used to probe
structural and electronic characteristics of graphite materials,
providing useful information on the defects (D-band), in-plane
vibration of sp2 carbon atoms (G-band), as well as the stacking
orders (2D-band).5 The G-band of graphite materials is a doubly
degenerate (TO and LO) phonon mode (E2g symmetry) at the
Brillouin zone center,6 whereas the D-band is due to phonon
branches around the K point and requires a defect for its
activation.5 The evolution of the 2D-band for different graphene
sheets has been used for determining graphene thickness as well
as for probing electronic structures through the double resonance
process.7,8 The symmetric and sharp 2D-band (～30 cm-1) can
be used as a detector for monolayer graphene.7,8
